Sulfur Dioxide
What is sulfur dioxide (SO2) gas?
Sulfur dioxide (SO₂) is a colorless, toxic gas with a sharp, irritating odor. Composed of sulfur and oxygen atoms, it is a major air pollutant and a key intermediate in industrial chemistry. SO₂ dissolves readily in water, forming sulfurous acid (H₂SO₃), and is distinct from its liquid or aqueous forms.
What are the key physical properties of SO2 gas?
State: Colorless gas (liquefies under moderate pressure).
Odor: Pungent, detectable at concentrations as low as 0.3–1.4 ppm.
Boiling Point: –10°C (14°F).
Density: 2.26 times heavier than air.
Solubility: Highly soluble in water (94 g/L at 20°C).
Critical Parameters & Concentration:
Molecular Weight: 64.07 g/mol.
CAS Number: 7446-09-5.
Purity: Industrial-grade SO₂ typically exceeds 99.9% for applications like semiconductor manufacturing.
UN Number: UN1079 (classified as Class 2.3 Toxic Gas and Class 8 Corrosive).
What are the primary industrial uses of SO₂ gas?
SO₂ is indispensable across sectors:
Chemical Manufacturing: Production of sulfuric acid (H₂SO₄), sulfites, and sulfates.
Food & Beverage: Preservative and bleaching agent for dried fruits, wines, and starch.
Semiconductors: Precision etching of silicon wafers.
Pharmaceuticals: Intermediate in drug synthesis and sterilization processes.
Metallurgy: Ore processing and metal refining.
How is SO₂ gas transported internationally?
Global transport adheres to strict protocols:
Packaging: High-strength steel cylinders or ISO tanks with corrosion-resistant linings.
Regulatory Compliance: Classified under IMDG, IATA, and DOT regulations. Requires hazard labels for toxicity (2.3) and corrosivity (8).
Safety Measures: Prohibited from mixing with flammables, oxidizers, or food-grade chemicals. Transported in ventilated vehicles, avoiding sunlight and populated areas.
What are best practices for storing SO₂ gas?
Safe storage demands:
Environment: Cool, dry, well-ventilated facilities away from moisture and heat sources.
Material Compatibility: Use stainless steel or PTFE-lined containers to prevent corrosion.
Leak Prevention: Install gas detectors, emergency scrubbers, and PPE (acid-resistant gloves, respirators).
What are emerging trends in SO₂ applications?
Growing demand in renewable energy sectors for battery production and flue gas desulfurization (FGD) systems. Innovations in encapsulated SO₂ solutions are reducing handling risks.
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